| 1964 |
Founding of the College by the Founder Patron, Mar Sebastian Vayalil. Rt. Rev. Msgr. Philip Valiyil appointed as Manager. Rev. Dr. N. M. Thomas appointed as Principal. Rev. Fr. Joseph kurias appointed as Bursar. |
| 1967 |
B.Sc.Maths, B.Sc.Physics, B.Sc.Chemistry, B.Sc.Botany, B.Sc.Zoology, B.A.English and B.A.Economics courses started. |
| 1967-1968 |
Rev. Sr. Mary Rosula C.M.C. takes over as Principal. |
| 1970 |
Inauguration of the Library and Auditorium Block. |
| 1973 |
Rev. Sr. Mary Mercy S.A.B.S. takes over as Principal. |
| 1974 |
Rt. Rev. Dr. Joseph Pallickaparampil takes over as Manager. |
| 1978 |
Starting of the College Canteen. |
| 1979 |
Rev. Sr. Pelagia S.H. takes over as Principal. |
| 1981 |
Rt. Rev. Dr. Joseph Pallickaparampil becomes Patron of the College. Rt. Rev. Msgr. Kurian Vanchipurackal takes over as Manager. B.A. History and M.Sc. Zoology courses started. |
| 1983 |
Inauguration of the Bishop Vayalil Block. |
| 1984 |
Rt. Rev. Dr. Joseph Mattom takes over as Manager. Rev. Sr. Anne Teresa F.C.C. takes over as Principal. |
| 1988 |
Celebration of the Silver Jubilee of the College. |
| 1989 |
Inauguration of the Silver Jubilee Memorial Block. |
| 1990 |
Rev. Sr. Meletia C.M.C. takes over as Principal. |
| 1993 |
Computer Courses Started. Inauguration of the Conference Hall. |
| 1994 |
Inauguration of the new Alphonsa Book Stall & Co-operative Store |
| 1995 |
Rev. Msgr. Philip Njaralakkattu takes over as Manager. Rev. Dr. Sr. Jessy Maria S.A.B.S. takes over as Principal. M.A. Politics course started. Rev. Fr. Joseph Kollamparampil appointed as Bursar. |
| 1996 |
Alphonsa Institute of Computer Studies started. |
| 1998 |
B.Sc Clinical Nutrition and Dietetics course started. Diploma course in Fashion Technology and Garment Designing started. |
| 1999 |
O’ Level Computer Course with recognition from Govt. of India started. |
| 2000 |
Rev. Sr. Marykutty Paul S.H. takes over as Principal. B.Sc. Physics - Vocational with Computer Application started. First accreditation by NAAC. |
| 2001 |
Inauguration of the Alphonsa Fitness Centre. |
| 2002 |
Full Accreditation to the O’ Level Computer Course. |
| 2003 |
Inauguration of Ruby Jubilee Celebrations. |
| 2004 |
Inauguration of the Basketball court. Rt. Rev. Dr. Joseph Kallarangattu becomes Patron of the College. Ruby Jubilee Valedictory Celebrations. |
| 2005 |
Inauguration of the website. M.Sc. Clinical Nutrition course started. Very Rev. Fr. Enas Ottathengumkal takes over as manager. Rev. Sr. Marykutty T.T. (Sr. Jais C.M.C.) takes over as Principal. Career oriented courses started. All Kerala Bishop Vayalil Birth Centenary Memorial Intercollegiate Volleyball Tournment for Women instituted. |
| 2006 |
Extension of Principal's room. Rev. Fr. Jose Pulavelil appointed as Bursar. |
| 2007 |
College reaccredited by NAAC |
| 2009 |
Rev. Sr. Dr. Celine Mathew takes over as Principal |